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Barcelona suffered defeat by lowly Leganés and Real Madrid also lost but Juventus and Paris maintained perfect league starts.
Having let a lead slip late on last time out, Tottenham will look to recover against Barcelona, who began with a bang.
Napoli are looking to capitalise on home advantage against a Liverpool side lifted by a late win in their first Group C game.
PSV Eindhoven are aiming to bounce back from a heavy opening defeat against Inter, buoyed by a late turnaround.
Paris suffered a late setback on matchday one and now take on a Crvena zvezda side in their first away group game.
Having picked up a useful away point in their first game, Porto's first home Group D game is against a vibrant Galatasaray.
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© ProSoccerUSA
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Atlético Madrid came back to win their first game, and now take on a Clube Brugge side on a seven-match losing run.
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Beaten in their first Group D fixture, Lokomotiv Moskva will look to get back on track with the visit of Schalke.
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Phil Jones missed the decisive penalty as Frank Lampard's Derby stunned Manchester United in the League Cup.
Phil Jones missed the decisive penalty as Frank Lampard's Derby stunned Manchester United in the League Cup.
CSKA Moskva have struggled at home in recent times, and face another tall order as Real Madrid come to Russia.
There has been little between Manchester United and Valencia, with five draws in eight previous meetings.
Having opened with an away win, Juventus will seek to cement their solid start to Group H at home to debutants Young Boys.
Former Milan striker Andriy Shevchenko is the first UEFA Champions League centurion in the spotlight.
