Liverpool return to the scene of last season's final triumph to take on an Atlético Madrid side with a formidable home European record.
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Tottenham are in the round of 16 for the third year running and take on Leipzig, making their first knockout appearance.
Atalanta's dream debut continues with a last-16 tie against Valencia, seeking a first quarter-final appearance since 2007.
Ciro Immobile hit a hat-trick against Sampdoria to move six points ahead of Robert Lewandowski and Timo Werner.
St-Pierroise from Reunion are in the French Cup round of 32; reach Europe and they could break records.
Barcelona head into the last 16 aiming to extend an unprecedented streak of 35 home matches undefeated. UEFA.com pores over all the competition's milestones.
Ciro Immobile has moved a goal ahead of Robert Lewandowski at the summit, with Timo Werner another goal behind.
Who is in Cristiano Ronaldo's sights? How far ahead is Lionel Messi? Meet the round of 16 teams' top marksmen
Yet to lose after 20 games, will Liverpool be the 34th side to end a 21st-century European top division unbeaten?
Yet to lose after 20 games, will Liverpool be the 34th side to end a 21st-century European top division unbeaten?
