Neither Hoffenheim nor Shakhtar Donetsk have recorded a win to date, but both could still progress from Group F.
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CSKA Moskva will be looking for another home win against Plzeň to stay in contention for a place in the round of 16.
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AEK Athens and Ajax have contrasting targets when they meet in Greece, but both need victory.
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Bayern have never lost to Benfica in nine previous matches and a draw would be enough to confirm progress.
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Lyon earned a famous win at Manchester City on matchday one but the English club now hold the Group F advantage.
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Juventus suffered a late setback last time out but a draw against Valencia would be enough to reach the round of 16.
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Manchester United are looking to reach the round of 16 as Young Boys switch their attention to finishing third.
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Roma will once again rely on their home form against Real Madrid with the teams level on nine Group G points.
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Two-time winner Andrea Pirlo is the latest UEFA Champions League centurion under the spotlight.
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Atlético Madrid are closing in on the round of 16 while Monaco are out and now seeking to end a long winless run.
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Borussia Dortmund missed the chance to confirm progress on matchday four, and now face a buoyant Club Brugge.
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Only a win will do for Galatasaray at eliminated Lokomotiv Moskva, who still harbour hopes of finishing third in Group D.
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Napoli could secure progress with a win but will be wary of Crvena zvezda, who claimed a notable scalp last time out.
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Tottenham welcome Internazionale for a crucial Group B game with the Italian side holding a three-point advantage.
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In a tight Group C, Paris Saint-Germain take on Liverpool, who have struggled away, in a potentially pivotal fixture.
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PSV Eindhoven are playing for third place against Barcelona, who are looking to win their section for the record 20th time.
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