The Argentine will take on his former mentor Pep Guardiola with his new club after being closely linked to a City move himself
Paris Saint-Germain will take on Manchester City in one of the biggest early draws of the Champions League group stage, while holders Chelsea will face Juventus and Barcelona and Bayern Munich will also square off following today's draw in Nyon.
The draw so far
Group A: Manchester City, PSG
Group B: Atletico Madrid, Liverpool
Group C: Sporting, Borussia Dortmund
Group D: Inter, Real Madrid
Group E: Bayern Munich, Barcelona
Group F: Villarreal, Manchester United
Group G: Lille, Sevilla
Group H: Chelsea, Juventus