Having comfortably won their last three games against Shakhtar, a repeat would guarantee Manchester City's last-16 place.
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Lokomotiv Moskva and Bayer Leverkusen are level on three points in Group D, with the visitors needing a win in Russia.
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Having picked up their first UEFA Champions League point, Atalanta now need a first win as Dinamo Zagreb visit.
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Real Madrid have regrouped from a heavy defeat at Paris, who need only a point in Spain to secure first place in Group A.
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Two heavy defeats have left Crvena zvezda needing to beat a Bayern München side who can secure first place in Group B.
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Tottenham have taken a firm grip on second place in Group B, while Olympiacos have endured a tough campaign.
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Galatasaray can no longer progress from Group A, while Club Brugge have to win in Istanbul to keep their own hopes alive.
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As the Barcelona forward earns a share of the Liga hat-trick record, we see how they compare for trebles beyond that.
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Ahead of Matchday 4, UEFA.com looks at who's proved an unmissable asset and who might have been overlooked so far.
Who's likely to start, who might be left out and who is unavailable? UEFA.com predicts the line-ups.
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UEFA.com looks at the reverse fixtures from last time out to find out who might be worth giving the armband to on Matchday 4.
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