Bayer Leverkusen and Lokomotiv Moskva have never met but each will know the value of a positive start in Group D.
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Chelsea won the UEFA Europa League last season, beating an Arsenal side who had ousted Valencia in the semi-finals.
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Manchester City recorded two big wins against Shakhtar Donetsk in last season's group stage and are aiming for a repeat in Ukraine.
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Semi-finalists last season, Ajax have come through qualifying again to take on a LOSC Lille side featuring for the first time in seven years.
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Beaten in the round of 16 last season, Bayern München kick off Group B with a rematch of their 1991 semi-final against Crvena zvezda.
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Borussia Dortmund and Barcelona both had their campaigns ended by English teams in 2018/19 and now meet for the first time in 20 years.
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Lyon and Zenit reached the round of 16 of the 2018/19 UEFA Champions League and UEFA Europa League respectively.
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Atalanta's first UEFA Champions League match takes them to Croatia to take on Dinamo Zagreb, who are making their seventh group appearance.
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Slavia are making only their second group appearance, and kick off Group F with a trip to San Siro to take on Inter.
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Leipzig were paired with Portuguese giants on their 2017/18 debut and face a similar task this season against Benfica.
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Holders Liverpool came close to having their campaign ended by Napoli last season as the teams reconvene at the Stadio San Paolo.
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Atlético's 2018/19 campaign was ended by Juventus, although the Spanish side had recorded an impressive home win.
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Javi Martinez future still undecided with midfielder yet to discuss Bayern Munich contract extension
In the group stage for the first time since 1994, Salzburg kick off against a Genk side making their first appearance in eight years.
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Two-third of Liverpool's all-star attack, should you pick Mohamed Salah or Sadio Mané – or both?
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UEFA.com looks at the numbers to see which players have done well in the group stage in years gone by.
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Paris Saint-Germain have been full of goals in recent years, but is Neymar or Kylian Mbappé the better pick?
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What is each club's pedigree? Who are their key players, new faces and ones to watch? UEFA.com has all the answers.
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What is each club's pedigree? Who are their key players, new faces and ones to watch? UEFA.com has all the answers.
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What is each club's pedigree? Who are their key players, new faces and ones to watch? UEFA.com has all the answers.
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What is each club's pedigree? Who are their key players, new faces and ones to watch? UEFA.com has all the answers.
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